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Perspectives on solution processing of two-dimensional …
In 2015, Ti 3 CNT x was intercalated by TBAOH followed by manual shaking (reproduced from ref. [68] with permission from Royal Society of Chemistry) while double …
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Solid-State 1H and 27Al NMR Studies of DMSO-Kaolinite …
Increased quadrupolar constants were observed and showed the major perturbations of the local Al symmetry that resulted from DMSO intercalation. Both the 1 H and …
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An Organic Solvent-Assisted Intercalation and Collection
Second, intercalation is reinforced by DMSO, which is similar as most intercalating chemicals in Route I. Third, the well-known "similia similibus solventur" principle is adopted to …
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A two-dimensional solid-state 2H exchange NMR study of …
The molecular motion in the (powder) kaolinite:DMSO-d 6 intercalation compound has been studied by two-dimensional solid-state 2 H exchange NMR.The NMR data have …
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Energetics, Interlayer Molecular Structures, and Hydration …
We integrated density functional theory with dispersion scheme (DFT-D) with various experimental methods to investigate the intercalation of dimethyl sulfoxide (DMSO) in …
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De-Intercalation of Iodoplumbate (DMSO)
Through the temperature-dependent configurational entropic effect on coordination between iodoplumbate and dimethylsulfoxide (DMSO), a DMSO de-intercalation processing method is developed.
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Kaolinite:Dimethylsulfoxide IntercalateA Theoretical Study
Three models of the kaolinite:dimethylsulfoxide intercalate with 25, 50, and saturation of dimethylsulfoxide (DMSO) have been investigated by means of density functional …
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Role of Impurities in Kaolinite Intercalation and
Based on the TG result of kaolinite–DMSO intercalation complex, the formula of A12Si2O5(OH)4(DMSO)0.7 was obtained, with which the kaolinite–DMSO complex model …
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MoS2 nanosheets via electrochemical lithium-ion intercalation under
Here, we report on a simple and low-cost electrochemical intercalation process of MoS 2 crystals via DMSO-solvated lithium-ion, where lithium chloride (LiCl) is used as source …
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Intercalation in two-dimensional transition metal …
Both types are associated with the principle of intercalation and de-intercalation of ions (H + or Li-ion) into the electrode materials. In 1991, ... Electrochemical intercalation of the …
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2D MXenes: Synthesis, properties, and electrochemical
Among these, dimethyl sulfoxide (DMSO) was the foremost intercalating material that was used to swell the multilayered HF-etched MXenes. MXenes nanosheets obtained …
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Spectral and conductivity measurements insights on loading …
The intercalation process of dimethyl sulfoxide (DMSO) into kaolinite can be also influenced by several key factors, i.e. the solvent polarity plays a crucial role in the …
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Properties tuning and applications for two dimension …
Firstly, the principles of electrochemical intercalation of 2D materials and the modulation of the intercalation process are described. Besides, the changes in the structure, …
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Intercalation as a versatile tool for fabrication, property …
The underlying principle for the intercalation-based exfoliation is in increasing the interlayer spacing between individual 2D layers by inserting foreign species. ... (DMSO) z) as …
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Multifunctional wearable triboelectric nanogenerators …
Following centrifugation (5000 rpm, 5 cycles), the supernatant was discarded. Then, DMSO (Intercalation solvent, 25 mL) was added and stirred at room temperature for 12 h. …
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Spectral and conductivity measurements insights on
DMSO can be loaded onto kaolinite in two mechanisms; intercalation onto kaolinite crystallites and adsorption. Water influences the mode of bonding between DMSO and …
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First-Principles Understanding of the Staging Properties of …
Graphite-based dual-ion batteries are a promising alternative to the lithium-ion batteries for energy storage because of its potentially lower cost, higher voltage, and better …
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SEM images of the aggregated microcomposite obtained by …
DMSO intercalation into HCl activated (HK) and untreated (UnK) Egyptian kaolinites via four different techniques; reflux of DMSO/water mixture at 70 °C (R1), ball-milling with DMSO …
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Effect of dimethyl sulfoxide intercalation into kaolinite on …
XRD and FTIR results confirm the intercalation of DMSO into kaolinite, the intercalation process caused a significant increase in the isoelectric point. The results show …
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Hongfei Cheng
A hydrated kaolinite-methanol intercalation compound (Kaol-MeOH (hydrated)) was synthesized by utilizing kaolinite/dimethyl sulfoxide intercalation compound (Kaol-DMSO) as an …
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Ti3C2‐MXene Partially Derived …
Ti 3 C 2 nanosheets (Figure 1e) were ultimately obtained after dimethyl sulfoxide (DMSO) intercalation and ultrasonic exfoliation. Subsequently, ... The first-principles …
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dmso intercalation principle
·In principle the maximum degree of intercalation DI max can be achieved if the amount of reagent in the thin solution film on the Kaol particles is sufficient to form a complete …
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Techniques for MXene Delamination into Single-Layer …
solution (50%) at room temperature [11, 16]. This intercalation process resulted in the expansion of layer spacing and a large increase (about 15.4 Å) in the c-lattice parameter (c-LP) of ML …
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The impact of DNA intercalators on DNA and DNA …
Indeed, most intercalation reactions have been shown to be exothermic40,41,42. It could be interesting to further study the general applicability of this postulate to DNA binding by, for …
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Simultaneous intercalation of sodium ion and DMSO into …
MXene is one of the most recent additions to the family of two-dimensional materials. In this study, two groups of TiC MXenes (D refers to intercalated MXene with …
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DMSO Deintercalation in Kaolinite DMSO Intercalate: …
DMSO Intercalation: Structural Evolution by XRD, FTIR, and DSC X-ray diffraction patterns (Figure1) show the total displacement of the characteristic d 001 reflection peak of kaolinite …
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Electronic conductivity and structure of DMSO-solvated …
Consequently a correlation Ry/R vs stoichiometry which in principle can be given [10], assuming surface reactions to be negligible, would become unreliable. ... Comparison …
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Kinetic study of the intercalation process of …
A kinetic analysis of the intercalation process was carried out considering a mechanism of simultaneous reactions based on a model in which the intercalation process …
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Intermediate phase engineering towards efficient and stable …
In particular, Fig.3 (e), the vibrational images of C-H and S-O demonstrated the intercalation of DMSO. Moreover, They prepared CsPbI 2 Br films at 120 °C and the device …
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Intercalation of dimethyl sulphoxide in kaolinite: Molecular …
Molecular dynamics simulation was performed to study the intercalation of dimethyl sulphoxide (DMSO) in kaolinite at 300 K. Our results indicate that the simulated basal …
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